Thisdoublebondis located between the fourth and fifth carbon atoms of the 18-carbon sphingoid base.
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Note the addition of a restraining olefin (doublebond) bridge in (g).
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It is initiated by free-radical attack upon a lipid, resulting in the removal of a hydrogen atom from a methylene group adjacent to adoublebond.
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Saturated cyclic compounds contain single bonds only, whereas aromatic rings have an alternating (or conjugated)doublebond.
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This compound features a rare example of a stable, unhindered carbon-seleniumdoublebond.
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They have a long and flexible chain between the onium heads, except for thedoublebondof mivacurium.
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Each contains onedoublebondwithin its molecular structure.
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The compound is deprotonated on one side and protonated on another side, whereas a single bond and adoublebondare exchanged.
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Eachdoublebondhas two additional localized electrons, while each triple bond has four additional electrons (two pairs) between the bonded atoms.
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Oxidation at thedoublebondoccurs slowly in air, and is known as rancidification in foodstuffs or drying in coatings.
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The overall transformation is the conversion of the carbonsulfur bonds to a carboncarbondoublebond.
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Due to the nature of elimination, it can be applied to both small rings, and large rings containing adoublebond.
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The aldehydic carbon-oxygendoublebondcan also be subject to hydroformylation, which leads to formic acid and its esters.
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These materials exist as "cis" or "trans" isomers depending on the geometry of thedoublebond.
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Alkenes with a thiol group on both sides of thedoublebondare called enedithiols.
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